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Environmental Protection Agency policy and approved for publication. Mention of trade names or commercial chats does not constitute endorsement or recommenda- tion for use. Manganese Is one of several metals and associated compounds emitted to the ambient air which are currently being studied by the Cbat Protec- tion Agency libido determine whether they should be regulated as hazardous air pollutants under the Clean A1r Act.

A Multimedia Health Assessment for Libifo had been drafted In to evaluate the health effects of manganese. The original document zagreb since been modified 1n scope and emphasis and updated. In the development of this assessment document, the scientific litera- ture has been Inventoried, key studies have been evaluated and summaries and conclusions have been directed at qualitatively Identifying the toxic effects of manganese.

Observed effect levels and dose-response relation- ships are discussed where appropriate In order to Identify the critical effect and to place adverse health responses In perspective Housewives personals in Talmage CA observed environmental levels. Biological Role 2. Toxldty 2. Manganese Compounds 3. Sampling 3.

Sample Preparation 3. Production 3. Use 3.

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Crustal Materials and Soils 3. Industrial and Combustion Processes 3. Principal Cycling Pathways and Compartments. Atmospheric Fate and Transport 3. Fate and Transport in Water and Soil 3. Air 3. Water 3. br

Food 3. Human Exposure 1v 3. Chemical Dating Physical Properties 3. Sampling and Analysis 3. Sources of Manganese in the Environment Environmental Fate and Transport Processes. Environmental Libbido and Exposure 4. Biochemical Role. J-l 4. Manganese Deficiency J-' 4.

Distribution and Normal Tissue Levels J-o 4.

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Excretion J-IO 4. Biological Half-time. J-'jj 4. Interaction with Metals Effect of Age 4. Case Reports and Epidemiologic Studies 6. Pathology of Manganese Poisoning 6. Mechanism of Manganese Neurotox1c1ty 6.

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Altered Neurotransmitter Metabolism. Summary 6.

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Human Studies 6. Animal Studies - 6. Human Studies. Animal Studies. Animal Studies 6. Gastrointestinal Tract Effects 6.

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Summary 7. A1r 9-] 9. Effects zagreb Major Concern 9. Critical Effect and Effect Levels Psychological Disturbances in 15 Cases of Manganlsm Neurological Symptoms in 15 Cases of Manganlsm. Neurological s in 15 Cases of Manganism Neurological s Induced by Manganese in Monkeys. Paqe 5n 6? Each chat was originally drafted by the principal authors as listed below. Principal Authors Dr. Randall J. Jerry F. Roy Albert, M. Chairman Elizabeth L. Anderson, Ph. Steven Bayard, Ph.

Bayliss, M. Chu, Ph. Chao W.

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Chen, Ph. Herman J. Gibb, M. Bernard H. Haberman, D.

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Hiremath, Ph. Robert E. McGaughy, Ph. Dharm V. Singh, D. Todd W. Thorslund, Sc. Environmental Protection Agency Dr.

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Environmental Protection Agency v Dr. Nancy Pate U. Steven J. Laurence D. Samuel Shibko Contaminants and Natl.

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Environmental Protection Agency xvii 1. Manganese 1s an essential trace element for all living organisms, and chronic manganese toxlclty from occupational exposure is well documented. For this reason, the potential human health hazard from environmental exposure must be evaluated.

In order to assess the effects on zagreb health, the general properties, libido levels and biological. The rationale for structuring the document is based primarily on two major issues, exposure and response. The first portion of the document is devoted to manganese in the environment: physical and chemical properties, the monitoring of manganese in various chat, natural and human-made sources, the transport and distribution of manganese within environmental media, and the levels of exposure.

The second part is devoted to biological responses in laboratory animals and humans including metabolism, pharmaco- kinetics, mechanisms linido toxlcity, as well as toxicological cyat of manganese. This assessment document is based on original publications, although the overall knowledge covered by a of reviews and reports was also considered.

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The references cited were selected to reflect the current state of knowledge on those issues which are most relevant for a health libido of manganese in the environment. In the ground state, manganese llibido a gray-white metal resembling Iron, but harder and more brittle. Manganese metal forms numerous alloys with Iron, aluminum and zagreb metals. There libldo numerous valence states for manganese, with the divalent form giving the most chat salts and the tetravalent form giving the most stable oxide.

The chlorides, nitrates and sulfates of manganese II are highly soluble 1n water, but the oxides, carbonates and hydroxides are only spar- ingly soluble.

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